After and with Skype ver. 4.0, Skype Company introduced a new feature of multiple users login on a single Computer for Windows XP "Switch User" Feature. The following steps will show you how to create a new shortcut for opening a new Skype window with a different Skype User Account ID.
- Right click on the Desktop and select 'New' then select or click 'Shortcut'.
Copy the below line (with quotes) and paste it in the text box where it says "Type the location of the item".
"C:\Program Files\Skype\Phone\Skype.exe" /secondary
- Click 'Next'
- Give the new shortcut a new name 'Skype Multi Login'
- Click 'Finish'
Now You can run the new Skype multiple instances with different Skype IDs.